Martin硫烷脱水剂

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仲醇和叔醇脱水给出烯烃,而伯醇脱水后生成醚。参见Burgess脱水剂。



反应机理



反应实例







参考文献


1. McMurry, J. E., Fleming, M. P. J. Am. Chem. Soc.1974, 96, 4708-4709.

2. McMurry, J. E. Acc. Chem. Res. 1974, 7, 281-286.

3. Lai, Y.-H. A review. Org. Prep. Proced. Int. 1980, 12, 361-391.

4. McMurry, J. E. Acc. Chem. Res. 1983, 16, 405-411.

5. Liu, Z., Zhang, T., Li, Y. Tetrahedron Lett. 2001, 42, 275-277.

6. Mikami, K., Takahashi, K., Nakai, T. J. Am. Chem. Soc. 1990, 112,4035-4037.

7. Casimiro-Garcia, A., Micklatcher, M., Turpin, J. A., Stup, T. L,Cushman, M. J. Med. Chem. 1999, 42, 4861-4874.

8. Eguchi, T., Ibaragi, K., Kakinuma, K. J. Org. Chem. 1998, 63, 2689-2698.


本文来自  Name Reactions:A Collection of Detailed Mechanisms

and Synthetic Applications--Fifth Edition


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